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Answer

(b) Electronegativity is the measure of pulling power that atoms have for a shared pair of electrons in a covalent bond.

As you move down group 17 in the periodic table the electronegativity decreases because:

  1. The atomic radius increases; therefore, there is less pull on the outer electrons by the nuclear charge.
  2. The number of shells increases causing screening; therefore, there is less pull on the outer electrons by the nuclear charge.

(i) Shape is tetrahedral.

SiCl4

(ii) Shape is v-shaped

SCl2

(iii) Shape is pyramidal

PCl3

(iv) Silicon tetrachloride

(v) Sulfur dichloride has bonds with the least degree of polarity.